ABSTRACT

Surface tensions of the parts of the NaF + AlF3 + AlPO4 and NaF + AlF3 + NaVO3 molten systems were investigated at four cryolite ratios (CR) [CR = n(NaF)/n(AlF3)] varied between 1.5 and 3 (1.5, 2, 2.5, and 3). The maximum bubble pressure method was used for the determination of this physicochemical property. In general, small additions of AlPO4 to the NaF-AlF3 molten system cause a decrease of the surface tension. By melting NaVO3 at low concentrations, new species with lower covalence of bonds occur compared with bonds of species presented in molten NaF-AlF3.

Compounds

#	Formula	Name
1	AlF3	aluminum fluoride
2	F2HNa	sodium hydrogen fluoride
3	NaO3V	sodium vanadate
4	AlO4P	aluminum phosphate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	2 1	Surface tension liquid-gas, N/m ; Liquid	Mole fraction - 2; Liquid Temperature, K; Liquid	Liquid Air at 1 atmosphere	Maximal bubble pressure	18
POMD	2 1 4	Surface tension liquid-gas, N/m ; Liquid	Mole fraction - 2; Liquid Mole fraction - 1; Liquid Temperature, K; Liquid	Liquid Air at 1 atmosphere	Maximal bubble pressure	101
POMD	2 1 3	Surface tension liquid-gas, N/m ; Liquid	Mole fraction - 2; Liquid Mole fraction - 1; Liquid Temperature, K; Liquid	Liquid Air at 1 atmosphere	Maximal bubble pressure	84

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Surface Tension of the NaF + AlF3 + AlPO4 and NaF + AlF3+ NaVO3 Molten Systems

Kubikova, B.[Blanka], Tomaskova, Z.[Zuzana], Priscak, J.[Jozef]

ABSTRACT