Aqueous solubilities of ferrocene (bis(cyclopentadienyl)iron(II), C10H10Fe) were measured at temperatures within (313 to 433) K along a 5 MPa isobar. The activity coefficients of ferrocene in aqueous solutions at saturation were obtained employing three different approximations of the solute heat capacity difference, ?CP2. The relative rate of increase in aqueous solubility of ferrocene with temperature, (? ln x2/?T)P,s, is distinctly lower than the corresponding values in aromatic hydrocarbons naphthalene (C10H8) and anthracene (C14H10) possibly because of less endothermic solute-water interactions because of less contact surface of the ferrocene molecule.
Compounds
#
Formula
Name
1
C10H10Fe
ferrocene
2
H2O
water
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.