Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Ultrasonic Velocities and Densities of l-Phenylalanine, l-Leucine, l-Glutamic Acid, and l-Proline + 2 mol*L-1 Aqueous NaCl and 2 mol*L-1 Aqueous NaNO3 Solutions from (298.15 to 328.15) K

Riyazuddeen, Afrin, S.[Sadaf]
J. Chem. Eng. Data 2010, 55, 7, 2643-2648
ABSTRACT
Ultrasonic velocity and density values of l-phenylalanine, l-leucine, l-glutamic acid, and l-proline + 2 mol*L-1 aqueous NaCl and 2 mol*L-1 aqueous NaNO3 solutions have been measured for several molal concentrations of amino acids at different temperatures from T = (298.15 to 328.15) K. The isentropic compressibility values (?s) have been computed using the ultrasonic velocity and density data. The ?s values decrease with an increase in the molal concentration of amino acids as well as with temperature. The trends of variation of ?s with the variation in molal concentration of amino acids as well as with temperature have been discussed in terms of various interactions operative in solutions.
Compounds
# Formula Name
1 ClNa sodium chloride
2 H2O water
3 NNaO3 sodium nitrate
4 C9H11NO2 L-phenylalanine
5 C6H13NO2 L-leucine
6 C5H9NO4 L-glutamic acid
7 C5H9NO2 L-proline
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 8
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 7
  • POMD
  • 3
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 7
  • POMD
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 7
  • POMD
  • 4
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 42
  • POMD
  • 4
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 42
  • POMD
  • 4
  • 3
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 63
  • POMD
  • 4
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 63
  • POMD
  • 5
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 5; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 49
  • POMD
  • 5
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 5; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 49
  • POMD
  • 5
  • 3
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 5; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 63
  • POMD
  • 5
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 5; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 63
  • POMD
  • 6
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 6; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 49
  • POMD
  • 6
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 6; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 49
  • POMD
  • 6
  • 3
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 6; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 49
  • POMD
  • 6
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 6; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 49
  • POMD
  • 7
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 7; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 63
  • POMD
  • 7
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 7; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 63
  • POMD
  • 7
  • 3
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 7; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Linear variable-path acoustic interferometer
  • 63
  • POMD
  • 7
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 7; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 63