Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Benzoic and Salicylic Acids in Subcritical Water at Temperatures Ranging from (298 to 473) K

Kayan, B.[Berkant], Yang, Y.[Yu], Lindquist, E. J.[Edward J.], Gizir, A. M.
J. Chem. Eng. Data 2010, 55, 6, 2229-2232
ABSTRACT
The solubility of benzoic acid and 2-hydroxybenzoic acid (salicylic acid) in water was determined at temperatures ranging from (298 to 473) K under a constant pressure of 5 MPa. The mole fraction solubility of these acids was enhanced by about two orders of magnitude when the water temperature was raised from (298 to 423) K. A new approximation model was developed to predict the solubility of solid organic acids in subcritical water at elevated temperatures. Our new model gives a better prediction for the solubility of the two acids than the approximation models reported in the literature.
Compounds
# Formula Name
1 C7H6O2 benzoic acid
2 H2O water
3 C7H6O3 2-hydroxybenzoic acid
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 3
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 4
  • POMD
  • 3
  • 2
  • Mole fraction - 3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • Chromatography
  • 6