Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurements of the Vapor Pressures and p?T Properties for trans-1,3,3,3-Tetrafluoropropene (HFO-1234ze(E))

Tanaka, K.[Katsuyuki], Takahashi, G.[Gen], Higashi, Y.[Yukihiro]
J. Chem. Eng. Data 2010, 55, 6, 2169-2172
ABSTRACT
The vapor pressures and p?T properties for trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) are measured using a metal-bellows cell. As for the vapor pressure, eight data points are obtained in the temperature range from (310 to 380) K and pressure range from (703 to 3458) kPa. The data of the vapor pressure is correlated by the Wagner type equation with the absolute average deviation of 0.02 %. By extrapolating the vapor-pressure correlation to the critical temperature, the critical pressure is determined to be 3632 kPa. The acentric factor is also determined to be 0.296 by using the vapor-pressure correlation. As for the p?T properties, 26 data points are obtained in the temperature range from (310 to 370) K and pressure range from (2000 to 5000) kPa. The data of the p?T properties are correlated by the Sato equation with the absolute average deviation of 0.04 %. Seven data points of the saturated liquid density are obtained by extrapolating the correlation of the p?T properties to the vapor pressure.
Compounds
# Formula Name
1 C3H2F4 trans-1,3,3,3-tetrafluoropropene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 8
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Bellows volumetry
  • 26