Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isothermal Vapor-Liquid Equilibrium Data for the Hexafluoropropylene (R1216) + Propylene System at Temperatures from (263.17 to 353.14) K

Coquelet, C.[Christophe], Valtz, A.[Alain], Naidoo, P.[Paramespri], Ramjugernath, D.[Deresh], Richon, D.[Dominique]
J. Chem. Eng. Data 2010, 55, 4, 1636-1639
ABSTRACT
Isothermal vapor-liquid equilibrium (VLE) data are presented for the system hexafluoropropylene (R1216) + propylene (R1270). Measurements were performed for six isotherms ranging from (263.17 to 353.14) K, at pressures from (0.224 to 4) MPa. The measurements were undertaken using a static-analytic type apparatus, with sampling of the equilibrium phases via pneumatic capillary samplers (Rolsi, Armine s patent). The apparatus and the samplers were developed in the CEP/TEP laboratory. The uncertainties in the measurements are within +- 0.02 K, +- 0.0005 MPa, and less than +- 4.0 % for temperature, pressure, and mole fractions, respectively. The full set of isothermal VLE data is correlated with the Peng-Robinson equation of state (PR EoS), incorporating the original Soave a function, with the Wong-Sandler mixing rule utilizing the nonrandom two-liquid (NRTL) activity coefficient model.
Compounds
# Formula Name
1 C3H6 propene
2 C3F6 hexafluoropropene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 6
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 87
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 81