ABSTRACT

Electrolytic conductivities, densities, viscosities, and refractive indices of some lithium halides (LiCl, LiBr, and LiI) have been studied in mass fraction (0.10, 0.20, and 0.30) of ethylene glycol monomethyl ether + methyl alcohol mixtures at 303.15 K. The limiting molar conductivities (?0), association constants (KA), and the distance of closest approach of the ion (R) have been evaluated using the Fuoss conductance equation (1978). The Walden product is obtained and discussed. The limiting apparent molar volumes (Vdeg ), experimental slopes (SV*) derived from the Masson equation, and viscosity A and B coefficients using the Jones-Dole equation have been interpreted in terms of ion-ion and ion-solvent interactions, respectively.

Compounds

#	Formula	Name
1	CH4O	methanol
2	C3H8O2	2-methoxyethan-1-ol
3	BrLi	lithium bromide
4	ClLi	lithium chloride
5	ILi	lithium iodide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	1	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	Pycnometric method	1
POMD	2	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	2	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	Pycnometric method	1
POMD	1 2	Viscosity, Pa*s ; Liquid	Mass fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	5
POMD	1 2	Mass density, kg/m3 ; Liquid	Mass fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Pycnometric method	5
POMD	1 2 4	Molar conductivity, S*m2/mol ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	dip-type immersion conductivity cell	30
POMD	1 2 4	Viscosity, Pa*s ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	18
POMD	1 2 4	Refractive index (Na D-line) ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	18
POMD	1 2 4	Mass density, kg/m3 ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	18
POMD	1 2 3	Molar conductivity, S*m2/mol ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	dip-type immersion conductivity cell	30
POMD	1 2 3	Viscosity, Pa*s ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	18
POMD	1 2 3	Refractive index (Na D-line) ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	18
POMD	1 2 3	Mass density, kg/m3 ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	18
POMD	1 2 5	Molar conductivity, S*m2/mol ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	dip-type immersion conductivity cell	30
POMD	1 2 5	Viscosity, Pa*s ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	18
POMD	1 2 5	Refractive index (Na D-line) ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	18
POMD	1 2 5	Mass density, kg/m3 ; Liquid	Solvent: Mass fraction - 2; Liquid Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	18

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Ion-Solvent Interactions of Some Halides of Common Cations with Organic Solvent Mixtures by Conductometric, Volumetric, Viscometric, and Refractometric Techniques

Roy, M. N.[Mahendra Nath], Dewan, R. K., Sarkar, L.[Lovely]

ABSTRACT