Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibria in Binary Systems Formed by n-Hexane with Alcohols

Gierycz, P.[Pawel], Kosowski, A.[Andrzej], Swietlik, R.[Ryszard]
J. Chem. Eng. Data 2010, 55, 2, 937-940
ABSTRACT
The modified witoslawski ebulliometer was used for the accurate determination of vapor-liquid equilibria in binary isothermal systems formed by n-hexane with the following: 2-butanol at (313.15, 323.15, and 333.15) K, 2-pentanol at (313.15, 323.15, 333.15, and 338.15) K, and 2-methyl-2-butanol at (313.15, 323.15, 333.15, and 338.15) K. The vapor pressures of the pure substances are also given. The experimental data have been compared with literature data (if available) of those systems and correlated by means of the Redlich-Kister, nonrandom two-liquid (NRTL), and Wilson equations.
Compounds
# Formula Name
1 C4H10O butan-2-ol
2 C6H14 hexane
3 C5H12O pentan-2-ol
4 C5H12O 2-methylbutan-2-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO::UFactor:3
  • 3
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO::UFactor:3
  • 4
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:3
  • 4
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO::UFactor:4
  • 4
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:3
  • 55
  • POMD
  • 2
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:3
  • 89
  • POMD
  • 4
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 77