Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurements of the Isobaric Specific Heat Capacity and Density for HFO-1234yf in the Liquid State

Tanaka, K.[Katsuyuki], Higashi, Y.[Yukihiro], Akasaka, R.[Ryo]
J. Chem. Eng. Data 2010, 55, 2, 901-903
ABSTRACT
The isobaric specific heat capacity and density of the HFO-1234yf (2,3,3,3-tetrafluoropropene, CH2-CFCF3) in the liquid state have been measured in the temperature range from (310 to 360) K at pressures up to 5 MPa. The uncertainties in temperature, pressure, isobaric specific heat capacity, and density measurements were estimated to be less than 5 mK, 3 kPa, 5 %, and 0.2 %, respectively. A sample with purity of 99.99 mol % or greater was used for the measurement. Experimental values for the isobaric specific heat capacity were correlated as a function of pressure along isotherms, and those for density were correlated as functions of pressure and temperature. In addition, the saturated liquid isobaric specific heat capacity and density were obtained from extrapolation of these correlations to the vapor pressure.
Compounds
# Formula Name
1 C3H2F4 2,3,3,3-tetrafluoro-1-propene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Thermal relaxation method
  • 22
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 23