Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isothermal Vapor-Liquid Equilibrium Data of 1,1,1,2-Tetrafluoroethane (R134a) + Dimethylformamide (DMF) Working Fluids for an Absorption Heat Transformer

Zehioua, R.[Raouf], Coquelet, C.[Christophe], Meniai, A. H.[Abdeslam Hassen], Richon, D.[Dominique]
J. Chem. Eng. Data 2010, 55, 2, 985-988
ABSTRACT
Vapor-liquid equilibrium data of 1,1,1,2-tetrafluoroethane (R134a) + dimethylformamide (DMF) were measured in the temperature range from (303.30 to 353.24) K by the static analytic method. The results are of interest to test the possibility of using R134a as a refrigerant in combination with an organic absorbent, that is, DMF, in an absorption heat transformer. The experimental data are correlated using the Peng-Robinson equation of state in combination with the Mathias-Copeman a function, MHV1 mixing rules, and the non-random two liquid (NRTL) activity coefficient model. We have compared our experimental results to predictions obtained using the predictive Soave-Redlich-Kwong (PSRK) group contribution equation of state.
Compounds
# Formula Name
1 C3H7NO dimethylformamide
2 C2H2F4 1,1,1,2-tetrafluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 12
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 54