ABSTRACT

The experimental densities of binary mixtures of cyclohexanone with 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, and 1-chlorobutane have been measured at T = (288.15, 298.15, 308.15, and 318.15) K and atmospheric pressure, over the whole composition range. From these results, excess molar volumes, VE, have been calculated and fitted to Redlich-Kister polynomial equation. The excess molar volumes are negative for the cyclohexanone + 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, and 1-chlorobutane systems and positive for the other three systems, over the whole composition range and at all investigated temperatures. The variation of these properties with the composition of the binary mixtures is discussed in terms of molecular interactions between components and structural effects.

Compounds

#	Formula	Name
1	C6H10O	cyclohexanone
2	C2H2Cl4	1,1,2,2-tetrachloroethane
3	C2H3Cl3	1,1,1-trichloroethane
4	CHCl3	trichloromethane
5	C2H4Cl2	1,2-dichloroethane
6	C3H6Cl2	1,3-dichloropropane
7	C4H8Cl2	1,4-dichlorobutane
8	C4H9Cl	1-chlorobutane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44
POMD	1 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44
POMD	1 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44
POMD	1 8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	44

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K

Ciocirlan, O.[Oana], Teodorescu, M.[Mariana], Dragoescu, D.[Dana], Iulian, O.[Olga], Barhala, A.[Alexandru]

ABSTRACT