Solubility of 2,6-Diamino-3,5-dinitropyridine and 2,5-Dihydroxyterephthalic Acid in N,N-Dimethylformamide, Dimethylsulfoxide, Ethanol, and Methanol, N,N-Dimethylacetamide, and Acetic Acid
Wang, Y.-H.[Yan-Hong], Hu, Z.[Zhen], Long, J.[Jun], Meng, X.-L.[Xiang-Li], Song, Y.-J.[Yuan-Jun], Huang, Y. D.
Solubility was reported for 2,6-diamino-3,5-dinitropyridine in N,N-dimethylformamide at (304.15 to 357.15) K, dimethylsulfoxide at (304.15 to 339.15) K, ethanol at (305.15 to 340.15) K, methanol at (293.15 to 339.15) K, and 2,5-dihydroxyterephthalic acid in N,N-dimethylformamide at (298.15 to 370.15) K, dimethylsulfoxide at (293.15 to 342.15) K, N,N-dimethylacetamide at (318.15 to 355.55) K, and acetic acid at (320.15 to 369.15) K. Results of these measurements are fitted with the combined binary solvent Margules equation. For the systems studied, the Margules equation is found to provide reasonable mathematical representation, with the average deviations between experimental values and calculated ones being on the order of +- 1.0 % and +- 0.2 % or less. Furthermore, the coupler parameters of the Margules equation (A21, A12) and the enthalpy of fusion (?fusH) were obtained by the Levenberg-Marquardt method and Global Optimization method.
Compounds
#
Formula
Name
1
C5H5N5O4
2,6-diamino-3,5-dinitropyridine
2
C2H6O
ethanol
3
CH4O
methanol
4
C3H7NO
dimethylformamide
5
C2H6OS
dimethyl sulfoxide
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.