ABSTRACT

The excess molar volumes (VE) and viscosity deviations (??) have been calculated from experimental density (?) and viscosity (?) data of the binary mixtures of 1,3-dioxolane (DO) with 2-methoxyethanol (ME), 2-ethoxyethanol (EE), 2-butoxyethanol (BE), 2-propylamine (PA), and cyclohexylamine (CA) measured over the entire range of composition at 298.15 K. Moreover, deviations in isentropic compressibility (?KS) and molar refraction (?R) have been calculated from ultrasonic speed of sounds (u) and refractive indices (nD) of the mixtures, respectively. The excess or deviation properties were fitted to the Redlich-Kister polynomial equation to derive the adjustable parameters (Ak) and corresponding standard deviations (?).

Compounds

#	Formula	Name
1	C3H6O2	1,3-dioxolane
2	C3H8O2	2-methoxyethan-1-ol
3	C4H10O2	2-ethoxyethan-1-ol
4	C6H14O2	2-butoxyethan-1-ol
5	C3H8O	propan-2-ol
6	C6H13N	cyclohexylamine

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	11
POMD	2 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Standard Abbe refractometry	11
POMD	2 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	2 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Pycnometric method	11
POMD	3 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	11
POMD	3 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Standard Abbe refractometry	11
POMD	3 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	3 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Pycnometric method	11
POMD	4 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	11
POMD	4 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Standard Abbe refractometry	11
POMD	4 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	4 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Pycnometric method	11
POMD	5 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	11
POMD	5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Standard Abbe refractometry	11
POMD	5 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Pycnometric method	11
POMD	6 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	11
POMD	6 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Standard Abbe refractometry	11
POMD	6 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Pycnometric method	11

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, Refractive Index, and Ultrasonic Speed of Binary Mixtures of 1,3-Dioxolane with 2-Methoxyethanol, 2-Ethoxyethanol, 2-Butoxyethanol, 2-Propylamine, and Cyclohexylamine

Sarkar, L.[Lovely], Roy, M. N.[Mahendra Nath]

ABSTRACT