ABSTRACT

Densities and viscosities of the binary mixtures of methyl 4-chlorobutyrate with benzene, toluene, o-xylene, m-xylene, and p-xylene have been measured at different temperatures (298.15, 308.15 and 318.15) K and atmospheric pressure over the whole range of compositions. The excess molar volumes were calculated from the experimental data and correlated by the Redlich-Kister polynomial equation. McAllister s threebody and four-body interaction models are also used to correlate the kinematic viscosities of these binary mixtures.

Compounds

#	Formula	Name
1	C6H6	benzene
2	C7H8	toluene
3	C8H10	1,2-dimethylbenzene
4	C8H10	1,3-dimethylbenzene
5	C8H10	1,4-dimethylbenzene
6	C5H9ClO2	methyl 4-chlorobutanoate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	2
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	1 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	1 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	2 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	2 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	3 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	3 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	4 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	4 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	5 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	5 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Viscosities of Binary Mixtures of Methyl 4-Chlorobutyrate with Aromatic Hydrocarbons at T ) (298.15 to 318.15) K

Yang, J.-H.[Jian-Hai], Dai, L.-Y.[Li-Yan], Wang, X.-Z.[Xiao-Zhong], Chen, Y.-Q.[Ying-Qi]

ABSTRACT