Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure

Fan, W.[Wei], Zhou, Q.[Qing], Sun, J.[Jian], Zhang, S.[Suojiang]
J. Chem. Eng. Data 2009, 54, 8, 2307-2311
ABSTRACT
Densities and viscosities for the methyl methacrylate (MMA) and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) ionic liquid binary system, over the whole concentration range in the temperature range from (283.15 to 353.15) K, were measured by using an Anton Paar DMA 5000 densimeter and an Anton Paar AMVn Measuring Assembly, respectively. The excess molar volumes VE were calculated by using the measured experimental densities and correlated by the Redlich-Kister type equation. The correlation results are in good agreement with the experimental data, and optimal fitting parameters are present. All the VE values within the scope of research are negative and become more and more negative with increasing temperature.
Compounds
# Formula Name
1 C5H8O2 methyl methacrylate
2 C8H15F6N2P 1-butyl-3-methylimidazolium hexafluorophosphate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CAPTUB:UFactor:4
  • 13
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • VIBTUB:UFactor:8
  • 13
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CAPTUB:UFactor:4
  • 13
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • VIBTUB:UFactor:8
  • 13
  • POMD
  • 1
  • 2
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CAPTUB:UFactor:4
  • 143
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • VIBTUB:UFactor:8
  • 143