Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Carbon Dioxide in Aqueous Solutions of N-Methyldiethanolamine and Piperazine in the High Gas Loading Region

Bottger, A.[Arne], Ermatchkov, V.[Viktor], Maurer, G.[Gerd]
J. Chem. Eng. Data 2009, 54, 6, 1905-1909
ABSTRACT
A synthetic technique was used to measure the solubility of carbon dioxide in three aqueous solutions of 2,2 -methyliminodiethanol (N-methyldiethanolamine, MDEA) and piperazine (PZ) at around (313, 333, 353, and 393) K and pressures between about (0.2 and 10) MPa. The molalities of (MDEA + PZ) in the aqueous solutions were (2.2 + 1.97), (4.22 + 2.01), and (7.83 + 2.07), respectively. The loading of the amines by carbon dioxide (i.e., the molar ratio of (MDEA + PZ) and CO2 varied between 0.2 and 2.0 The new experimental results are to supplement previously published experimental data of our research group for a single solution of both amines {molalities of (MDEA + PZ) in the aqueous solutions: (2.0 + 2.0)}. The new experimental results are compared to predictions from a model that combines previously published models for (CO2 + MDEA + H2O) and (CO2 + PZ + H2O).
Compounds
# Formula Name
1 C5H13NO2 N-methyldiethanolamine
2 C4H10N2 piperazine
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Molality, mol/kg - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 24