ABSTRACT

Isobaric vapor-liquid equilibrium (VLE) were measured for the ternary system methylbutyl ketone + 1-pentanol + anisole and for constituent binaries methylbutyl ketone + anisole at the pressures (26.66, 53.33, 79.99, and 101.32) kPa and methylbutyl ketone + 1-pentanol at 101.32 kPa. We obtained boiling temperature-liquid composition (T-x) relations by using a semimicroebulliometer. The modified Wilson model with parameters that linearly depend on temperature was used to correlate the binary T-x data and to predict VLE in the ternary system.

Compounds

#	Formula	Name
1	C6H12O	2-hexanone
2	C5H12O	pentan-1-ol
3	C7H8O	anisole

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:3	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:2	4
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:3	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:2	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:3	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:2	4
POMD	3 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid Pressure, kPa; Liquid		Liquid Gas	EBULLIO:UFactor:2	40
POMD	2 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:2	8
POMD	2 3 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid Pressure, kPa; Liquid		Liquid Gas	EBULLIO:UFactor:2	74

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isobaric Vapor-Liquid Equilibria of the Ternary System Methylbutyl Ketone + 1-Pentanol + Anisole

Kirss, H.[Helle], Kuus, M.[Mati], Siimer, E.[Enn]

ABSTRACT