Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Synthesis and Physical Properties of 1-Ethylpyridinium Ethylsulfate and its Binary Mixtures with Ethanol and 1-Propanol at Several Temperatures

Gonzalez, B.[Begona], Calvar, N.[Noelia], Gomez, E.[Elena], Dominguez, I.[Irene], Dominguez, A.[Angeles]
J. Chem. Eng. Data 2009, 54, 4, 1353-1358
ABSTRACT
Ionic liquid 1-ethylpyridinium ethylsulfate, EpyESO4, was synthesized, and its experimental densities, speeds of sound, viscosities, and refractive indices from (298.15 to 343.15) K are reported. Densities, speeds of sound, isentropic compressibility, and dynamic viscosities for EpyESO4 + ethanol and + 1-propanol at temperatures T ) (298.15, 313.15, and 328.15) K were determined over the whole composition range at 0.1 MPa. The excess molar volumes, isentropic compressibilities, and viscosity deviations for ethanol (1) + EpyESO4 (2) and 1-propanol (1) + EpyESO4 (2) binary systems at the above-mentioned temperatures were calculated and satisfactorily fitted to the Redlich-Kister equation. Refractive indices of the binary mixtures were measured at 298.15 K over the whole composition range. The results were used to calculate deviations in the refractive index.
Compounds
# Formula Name
1 C2H6O ethanol
2 C3H8O propan-1-ol
3 C9H15NO4S 1-ethylpyridinium ethyl sulfate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB::UFactor:4
  • 3
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PULSEH::UFactor:3
  • 3
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:6
  • 3
  • POMD
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB::UFactor:4
  • 3
  • POMD
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PULSEH::UFactor:3
  • 3
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB::UFactor:6
  • 3
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 10
  • POMD
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 11
  • POMD
  • 3
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PULSEH:UFactor:3
  • 10
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:6
  • 10
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB::UFactor:4
  • 1
  • POMD
  • 1
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 33
  • POMD
  • 1
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 11
  • POMD
  • 1
  • 3
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PULSEH:UFactor:3
  • 33
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:6
  • 33
  • POMD
  • 2
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 36
  • POMD
  • 2
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 12
  • POMD
  • 2
  • 3
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PULSEH:UFactor:3
  • 36
  • POMD
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:6
  • 36