Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Determination, Correlation, and Prediction of Physical Properties of the Ternary Mixtures Ethanol and 1-Propanol + Water + 1-Ethyl-3-methylpyridinium Ethylsulfate at 298.15 K

Calvar, N.[Noelia], Gomez, E.[Elena], Gonzalez, B.[Begona], Dominguez, A.[Angeles]
J. Chem. Eng. Data 2009, 54, 8, 2229-2234
ABSTRACT
In this work, densities, F, refractive indices, nD, and dynamic viscosities, c, of the ternary mixtures of the alcohols ethanol and 1-propanol + water with 1-ethyl-3-methylpyridinium ethylsulfate [empy][eSO4] have been measured at T ) 298.15 K and atmospheric pressure. Excess molar volumes, VE, refractive index deviations, AnD, and viscosity deviations, Ac, have been calculated from experimental data and fitted to various correlation equations, obtaining good results. The excess properties have been used to test several prediction models, finding out that symmetric models give lower deviations than asymmetric models.
Compounds
# Formula Name
1 C2H6O ethanol
2 C3H8O propan-1-ol
3 H2O water
4 C10H17NO4S 1-ethyl-3-methylpyridinium ethylsulfate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:8
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB::UFactor:8
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:8
  • 13
  • POMD
  • 2
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 13
  • POMD
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 13
  • POMD
  • 1
  • 3
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CAPTUB:UFactor:8
  • 100
  • POMD
  • 1
  • 3
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 100
  • POMD
  • 1
  • 3
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 100