ABSTRACT

In this work, densities, speeds of sound, and refractive indices of 12 binary systems of cycloalkanes with aromatics (cyclopentane (1), or cyclohexane (1), or methylcyclohexane (1) + benzene (2), + toluene (2), + ethylbenzene (2)) at T ) 313.15 K and at atmospheric pressure were determined over the whole composition range. From the experimental results, the excess properties (excess molar volumes, isentropic compression, excess molar isentropic compression, and refractive deviations) at T ) 313.15 K of all studied binary systems were calculated and satisfactorily fitted to the Redlich-Kister equation.

Compounds

#	Formula	Name
1	C5H10	cyclopentane
2	C6H12	cyclohexane
3	C7H14	methylcyclohexane
4	C6H6	benzene
5	C7H8	toluene
6	C8H10	ethylbenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	OTHER::sMethod:Vibrating Tube Densimeter	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	OTHER::sMethod:Vibrating Tube Densimeter	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	OTHER::sMethod:Vibrating Tube Densimeter	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	OTHER::sMethod:Vibrating Tube Densimeter	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	OTHER::sMethod:Vibrating Tube Densimeter	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	6	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	OTHER::sMethod:Vibrating Tube Densimeter	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	4 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	4 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	5 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	6 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	6 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	4 2	Refractive index (Na D-line) ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	4 2	Speed of sound, m/s ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	4 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	5 2	Refractive index (Na D-line) ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	5 2	Speed of sound, m/s ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	5 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	6 2	Refractive index (Na D-line) ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	6 2	Speed of sound, m/s ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	6 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	4 3	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	4 3	Speed of sound, m/s ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	4 3	Mass density, kg/m3 ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	3 5	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	3 5	Speed of sound, m/s ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	3 5	Mass density, kg/m3 ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	6 3	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	13
POMD	6 3	Speed of sound, m/s ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating Tube Densimeter	13
POMD	6 3	Mass density, kg/m3 ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Speed of Sound, and Refractive Index for Binary Mixtures Containing Cycloalkanes and Aromatic Compounds at T = 313.15 K

Calvar, N.[Noelia], Gonzalez, B.[Begona], Gomez, E.[Elena], Canosa, J.[Jose]

ABSTRACT