Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric Behavior of the Binary Mixtures of Methyl Ethyl Ketone with n-Hexane, Cyclohexane, and Benzene at T ) (303.15, 313.15, and 323.15) K

Adhikhari, A. B.[Anath B.], Rahman, I. M. M.[Ismail M. M.], Uddin, M. A., Hasegawa, H.[Hiroshi], Majid, M. A.

J. Chem. Eng. Data 2009, 54, 3, 1138-1141

ABSTRACT

Experimental values of density of binary liquid mixtures of methyl ethyl ketone (MEK) with n-hexane, cyclohexane, and benzene have been measured at a number of mole fractions at T ) (303.15, 313.15, and 323.15) K. The excess molar volumes Vm E have been calculated from the density data. These quantities are further fitted to the appropriate polynomial equations. The sign and magnitude of the calculated excess values have been discussed in terms of the nature of the solvent-solvent interactions in binary mixtures.

Compounds

#	Formula	Name
1	C4H8O	butanone
2	C6H14	hexane
3	C6H12	cyclohexane
4	C6H6	benzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33