Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physicochemical Properties of Aqueous Hydroxylamine Sulfate and Aqueous (Hydroxylamine Sulfate + Ammonium Sulfate) Solutions at Different Temperatures

Fang, S.[Sheng], Zhang, J.-G.[Jian-Guo], Liu, J.-Q.[Jian-Qing], Liu, M.[Ming], Luo, S.[Sheng], He, C.-H.[Chao-Hong]
J. Chem. Eng. Data 2009, 54, 7, 2028-2032
ABSTRACT
The densities of an aqueous solution of pure hydroxylamine sulfate at T ) (283.15, 288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K and a solution of hydroxylamine sulfate containing ammonium sulfate at T ) (293.15, 298.15, 303.15, 308.15, and 313.15) K have been determined over a wide range of concentrations. The viscosities of binary and ternary mixtures of these compounds at T ) (298.15, 303.15, and 308.15) K are also presented. The Masson-type equation and extended Jones-Dole equation in terms of ionic strength are used to correlate the density and viscosity, respectively, of aqueous solutions of hydroxylamine sulfate. The ideal mixing rule of Young has been successfully applied to predict the ternary densities and viscosities of aqueous hydroxylamine sulfate + ammonium sulfate based on relevant binary solution properties.
Compounds
# Formula Name
1 H5NO5S hydroxylammonium hydrogen sulfate
2 H8N2O4S ammonium sulfate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 42
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 98
  • POMD
  • 3
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 3
  • POMD
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 5
  • POMD
  • 3
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Molality, mol/kg - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 45
  • POMD
  • 3
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 75