Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isothermal Vapor-Liquid Equilibrium Data for the Hexafluoroethane (R116) + Propane System at Temperatures from (263 to 323) K

Ramjugernath, D.[Deresh], Valtz, A.[Alain], Coquelet, C.[Christophe], Richon, D.[Dominique]
J. Chem. Eng. Data 2009, 54, 4, 1292-1296
ABSTRACT
Isothermal vapor-liquid equilibrium data are presented for the system hexafluoroethane (R116) + propane. Measurements were performed for six isotherms (three isotherms below and three above the critical temperature of R116) ranging from (263.3 to 323.19) K, with pressure ranging from (0.344 to 3.851) MPa. The measurements were undertaken using a static-analytic type apparatus, with sampling of the equilibrium phases via pneumatic capillary samplers (Rolsi, Armine s patent). The apparatus as well as the samplers were developed in the CEP/TEP laboratory. The uncertainties in the measurements were within ( 0.01 K, ( 0.0003 MPa, and less than 2.0 % for temperatures, pressures, and mole fractions, respectively. The full set of isothermal vapor-liquid equilibrium data was correlated with the Peng-Robinson equation of state, incorporating the Mathias-Copeman alpha function, with the Wong-Sandler mixing rule utilizing the NRTL activity coefficient model.
Compounds
# Formula Name
1 C2F6 hexafluoroethane
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 6
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 67
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 67