Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Mass Diffusion Coefficients of Oxygenated Fuel Additives in Diesel Oil and in Heptane at T ) (276 to 333) K

Zhong, Q.[Qiu], He, M.[Maogang], Guo, Y.[Ying], Zhang, Y.[Ying]
J. Chem. Eng. Data 2009, 54, 6, 1666-1671
ABSTRACT
Digital image holographic interferometry has been used to measure the mass diffusion coefficient of fluids. The mass diffusion coefficients of KCl in aqueous solution at a concentration pf 0.33 mol *dm-3 as the standard solution was used to verify the precision and reliability of the apparatus. The results show that the absolute average relative deviations is within 1.20 %. The uncertainty in mass diffusion coefficient is estimated to be not greater than ( 0.2 %. The mass diffusion coefficients of three different oxygenated fuel additives, bis(2-methoxyethyl)-ether (diethylene glycol dimethyl ether, DGM), 1,2-dimethoxyethane (ethyleneglycol dimethyl ether, GDME), and ethanol, were determined in both diesel oil and heptane at temperatures between (276 and 333) K.
Compounds
# Formula Name
1 C6H14O3 2,5,8-trioxanonane
2 C4H10O2 1,2-dimethoxyethane
3 C2H6O ethanol
4 C7H16 heptane
5 ClK potassium chloride
6 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 5
  • 6
  • Binary diffusion coefficient, m2/s ; Liquid
  • Mole fraction - 5; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Optical method
  • 1
  • POMD
  • 2
  • 4
  • Binary diffusion coefficient, m2/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Optical method
  • 21
  • POMD
  • 1
  • 4
  • Binary diffusion coefficient, m2/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Optical method
  • 21
  • POMD
  • 3
  • 4
  • Binary diffusion coefficient, m2/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Optical method
  • 21