Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibria of Water + Triethylene Glycol (TEG) and Water + TEG + Toluene at 85 kPa

Mostafazadeh, A. K.[Ali Khosravanipour], Rahimpour, M. R.[Mohammad Reza], Shariati, A.[Alireza]
J. Chem. Eng. Data 2009, 54, 3, 876-881
ABSTRACT
In this study, vapor-liquid equilibria data have experimentally been measured for systems water + triethylene glycol (TEG) and water + TEG + toluene at 85 kPa and various temperatures. The VLE data were determined in a modified Othmer still, and the samples were analyzed using gas chromatography and titration methods. The NRTL, UNIQUAC, and Van Laar models were used to correlate the data. The results demonstrate the enhancement of volatility of water in water + TEG solutions and increasing the purity of the dehydrated TEG by the addition of toluene. Using this method, the more concentrated TEG can be obtained in the stripping columns of the natural gas dehydration systems.
Compounds
# Formula Name
1 C6H14O4 triethylene glycol
2 H2O water
3 C7H8 toluene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32
  • 18
  • POMD
  • 1
  • 2
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 18
  • POMD
  • 3
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 2 ; Liquid
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Gas
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • Chromatography
  • Chromatography
  • Chromatography
  • 17