Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Activity Coefficients at Infinite Dilution of Organic Compounds in 1-Butyl-3-methylimidazolium Tetrafluoroborate Using Inverse Gas Chromatography

Revelli, A.-L.[Anne-Laure], Mutelet, F.[Fabrice], Turmine, M.[Mireille], Solimando, R.[Roland], Jaubert, J.-N.[Jean-Noel]
J. Chem. Eng. Data 2009, 54, 1, 90-101
ABSTRACT
Activity coefficients at infinite dilution ( A ) of organic compounds in the room-temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate were determined using inverse gas chromatography from (303.35 to 332.55) K. Retention data were used to estimate the influence of gas-liquid and gas-solid interfacial adsorption on the value of activity coefficients at infinite dilution of solutes in this ionic liquid. Most of the polar solutes were retained largely by partition, while n-alkanes were retained predominantly by interfacial adsorption on the ionic liquid studied. The solvation characteristics of the ionic liquid were evaluated using the Abraham solvation parameter model.
Compounds
# Formula Name
1 C8H15BF4N2 1-butyl-3-methylimidazolium tetrafluoroborate
2 C6H14 hexane
3 C6H14 3-methylpentane
4 C7H16 heptane
5 C8H18 2,2,4-trimethylpentane
6 C8H18 octane
7 C9H20 nonane
8 C6H12 methylcyclopentane
9 C6H12 cyclohexane
10 C7H14 methylcyclohexane
11 C7H14 cycloheptane
12 C6H6 benzene
13 C7H8 toluene
14 C8H10 ethylbenzene
15 C8H10 1,3-dimethylbenzene
16 C8H10 1,4-dimethylbenzene
17 C8H10 1,2-dimethylbenzene
18 C6H12 hex-1-ene
19 C6H10 1-hexyne
20 C7H12 1-heptyne
21 C4H8O butanone
22 C5H10O pentan-2-one
23 C5H10O pentan-3-one
24 C4H8O2 1,4-dioxane
25 CH4O methanol
26 C2H6O ethanol
27 C3H8O propan-1-ol
28 C3H8O propan-2-ol
29 C4H10O 2-methyl-1-propanol
30 C4H10O butan-1-ol
31 C2H3F3O 2,2,2-trifluoroethanol
32 C4H10O diethyl ether
33 C6H14O diisopropyl ether
34 CHCl3 trichloromethane
35 CH2Cl2 dichloromethane
36 CCl4 tetrachloromethane
37 C2H3N acetonitrile
38 CH3NO2 nitromethane
39 C3H7NO2 1-nitropropane
40 C6H15N triethylamine
41 C5H5N pyridine
42 C4H4S thiophene
43 CH2O methanal
44 C3H6O propanal
45 C4H8O butanal
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Activity coefficient - 2 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 3
  • 1
  • Activity coefficient - 3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 4
  • 1
  • Activity coefficient - 4 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 5
  • 1
  • Activity coefficient - 5 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 6
  • 1
  • Activity coefficient - 6 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 7
  • 1
  • Activity coefficient - 7 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 8
  • 1
  • Activity coefficient - 8 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 9
  • 1
  • Activity coefficient - 9 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 10
  • 1
  • Activity coefficient - 10 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 11
  • 1
  • Activity coefficient - 11 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 11; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 12
  • 1
  • Activity coefficient - 12 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 13
  • 1
  • Activity coefficient - 13 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 14
  • 1
  • Activity coefficient - 14 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 15
  • 1
  • Activity coefficient - 15 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 15; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 16
  • 1
  • Activity coefficient - 16 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 16; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 17
  • 1
  • Activity coefficient - 17 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 17; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 18
  • 1
  • Activity coefficient - 18 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 18; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 19
  • 1
  • Activity coefficient - 19 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 19; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 20
  • 1
  • Activity coefficient - 20 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 20; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 21
  • 1
  • Activity coefficient - 21 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 21; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 22
  • 1
  • Activity coefficient - 22 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 22; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 23
  • 1
  • Activity coefficient - 23 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 23; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 24
  • 1
  • Activity coefficient - 24 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 24; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 25
  • 1
  • Activity coefficient - 25 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 25; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 26
  • 1
  • Activity coefficient - 26 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 26; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 27
  • 1
  • Activity coefficient - 27 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 27; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 28
  • 1
  • Activity coefficient - 28 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 28; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 29
  • 1
  • Activity coefficient - 29 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 29; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 30
  • 1
  • Activity coefficient - 30 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 30; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 31
  • 1
  • Activity coefficient - 31 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 31; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 32
  • 1
  • Activity coefficient - 32 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 32; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 33
  • 1
  • Activity coefficient - 33 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 33; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 34
  • 1
  • Activity coefficient - 34 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 34; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 35
  • 1
  • Activity coefficient - 35 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 35; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 36
  • 1
  • Activity coefficient - 36 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 36; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 37
  • 1
  • Activity coefficient - 37 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 37; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 38
  • 1
  • Activity coefficient - 38 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 38; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 39
  • 1
  • Activity coefficient - 39 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 39; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 40
  • 1
  • Activity coefficient - 40 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 40; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 41
  • 1
  • Activity coefficient - 41 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 41; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 42
  • 1
  • Activity coefficient - 42 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 42; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 43
  • 1
  • Activity coefficient - 43 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 43; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 44
  • 1
  • Activity coefficient - 44 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 44; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4
  • POMD
  • 45
  • 1
  • Activity coefficient - 45 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 45; Liquid
  • Liquid
  • Gas
  • inverse gas chromatography
  • 4