Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation for Solubilities of Naphthalene in Acetone, Toluene, Xylene, Ethanol, Heptane, and 1-Butanol

Cui, T.-B.[Tie-Bing], Luo, T.-L.[Ting-Liang], Zhang, C.[Chen], Mao, Z.-B.[Zhi-Bo], Liu, G.-J.[Gou-Ji]
J. Chem. Eng. Data 2009, 54, 3, 1065-1068
ABSTRACT
Using a dynamic method, the solubilities of naphthalene in acetone, toluene, xylene, ethanol, heptane, and 1-butanol have been determined experimentally from (297.17 to 322.70, 291.35 to 334.65, 299.42 to 337.97, 304.26 to 339.76, 290.25 to 333.75, and 313.77 to 342.8) K, respectively. The experimental data were correlated with the Wilson model, Apelblat equation, and e-h model. The calculated results show that the correlation of the Wilson model for six measured systems has less deviation than that of the Apelblat equation and the e-h model.
Compounds
# Formula Name
1 C10H8 naphthalene
2 C3H6O acetone
3 C2H6O ethanol
4 C7H8 toluene
5 C7H16 heptane
6 C4H10O butan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DSC
  • 1
  • POMD
  • 1
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 2
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Ebulliometric method (Recirculating still)
  • 18
  • POMD
  • 3
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Ebulliometric method (Recirculating still)
  • 19
  • POMD
  • 1
  • 4
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Ebulliometric method (Recirculating still)
  • 12
  • POMD
  • 1
  • 5
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Ebulliometric method (Recirculating still)
  • 21
  • POMD
  • 6
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Ebulliometric method (Recirculating still)
  • 17