Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Hydrogen in the Cyclic Alkylene Ester 1,2-Butylene Carbonate

Kumelan, J.[Jacek], Tuma, D.[Dirk], Verevkin, S. P.[Sergey P.], Maurer, G.[Gerd]
J. Chem. Eng. Data 2008, 53, 12, 2844-2850
ABSTRACT
The solubility of hydrogen in the cyclic alkylene ester 1,2-butylene carbonate was determined at (283.3, 298.2, and 323.1) K up to a pressure of 9.3 MPa with a high-pressure view-cell technique based on the synthetic method. The solubility of hydrogen in 1,2-butylene carbonate increases with increasing temperature. An extension of Henry s law was employed to correlate the solubility pressures, and the final results for Henry s constant (at zero pressure) of hydrogen in 1,2-butylene carbonate (on the molality scale) are correlated within the experimental uncertainty (about ( 1.4 %) by ln(kH,H2 (0) /MPa) ) 2.123 + 650.96/(T/K).
Compounds
# Formula Name
1 H2 hydrogen
2 C5H8O3 1,2-butylene carbonate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 7
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 21