Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Sebacic Acid in Binary Mixtures Containing Alcohols

Chen, S.-n.[Su-ning], Xia, Q.[Qing], Lu, L.-f.[Li-fei], Li, D.[Dong], Zhang, F.-B.[Feng-Bao], Zhang, G.-L.[Guo-Liang]
J. Chem. Eng. Data 2009, 54, 3, 776-780
ABSTRACT
The solubilities of sebacic acid in mixed solvents n-propanol + water have been measured by a dynamic method using a laser monitoring observation technique over a temperature range (288 to 351) K. A synergistic effect on solubility was found to occur in sebacic acid + n-propanol + water mixed systems. To detect the synergistic effect, solubilities of sebacic acid in 14.35 %, 36.97 %, 79.81 %, and 90.00 % mole fraction ethanol aqueous solution were determined to supplement our previous report. A weak synergistic effect was found for sebacic acid + ethanol + water mixed systems. The solid-liquid equilibrium (SLE) data have been fitted using the eh equation, the Wilson equation, and the NRTL equation. The comparison between the experimental and the calculated solubilities for the three models is reasonable, and the root-meansquare deviations for each system range from (0.30 to 1.95) K.
Compounds
# Formula Name
1 C10H18O4 1,10-decanedioic acid
2 C2H6O ethanol
3 C3H8O propan-1-ol
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser monitoring
  • 20
  • POMD
  • 3
  • 1
  • 4
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Solvent: Mole fraction - 3; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser monitoring
  • 96
  • POMD
  • 2
  • 1
  • 4
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser monitoring
  • 67