Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Bis(benzoxazolyl-2-methyl) Sulfide in Different Pure Solvents and Ethanol + Water Binary Mixtures between (273.25 and 325.25) K

Yang, Z.-S.[Zu-Shou], Zeng, Z.-X.[Zuo-Xiang], Xue, W.-L.[Wei-Lan], Zhang, Y.[Ying]
J. Chem. Eng. Data 2008, 53, 11, 2692-2695
ABSTRACT
The solubilities of bis(benzoxazolyl-2-methyl) sulfide in ethanol, 1-butanol, 2-propanol, chlorobenzene, toluene, o-xylene, and ethanol + water were measured by a synthetic method. The laser monitoring observation technique was used to determine the disappearance of the solid phase in the solid + liquid mixture. All data were measured in the temperature range from (273.25 to 325.25) K at atmosphere pressure. The effect of solvent composition and temperature on the solubility was discussed. For all solvents studied, the data are well fitted with a semiempirical Apelblat equation.
Compounds
# Formula Name
1 CHNaO3 sodium bicarbonate
2 H2O water
3 C2H6O ethanol
4 C4H10O butan-1-ol
5 C3H8O propan-2-ol
6 C6H5Cl chlorobenzene
7 C7H8 toluene
8 C8H10 1,2-dimethylbenzene
9 C16H12N2O2S bis(benzoxazolyl-2-methyl) sulfide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 9
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 1
  • 2
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser monitoring observation technique
  • 5
  • POMD
  • 3
  • 9
  • Mole fraction - 9 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 12
  • POMD
  • 4
  • 9
  • Mole fraction - 9 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 10
  • POMD
  • 5
  • 9
  • Mole fraction - 9 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 10
  • POMD
  • 6
  • 9
  • Mole fraction - 9 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 10
  • POMD
  • 7
  • 9
  • Mole fraction - 9 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 10
  • POMD
  • 8
  • 9
  • Mole fraction - 9 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 10
  • POMD
  • 3
  • 2
  • 9
  • Mole fraction - 9 ; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 9
  • laser monitoring observation technique
  • 60