Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosity and Density of Five Hydrocarbon Liquids at Pressures up to 200 MPa and Temperatures up to 473 K

Caudwell, D. R.[Derek R.], Trusler, J. P. M.[J. P. Martin], Vesovic, V.[Velisa], Wakeham, W. A.[William A.]
J. Chem. Eng. Data 2009, 54, 2, 359-366
ABSTRACT
We report the results of simultaneous measurements of the viscosity and density of five pure hydrocarbon liquids (octane, decane, 1,3-dimethylbenzene, 1,2,3,4-tetrahydronaphthalene, and 1-methylnaphthalene) at temperatures between (298.15 and 473.15) K and at pressures ranging from 0.1 MPa to approximately 200 MPa. The measurements were made with a vibrating-wire instrument, and the estimated expanded relative uncertainties are ( 2 % for viscosity and ( 0.2 % for density with a coverage factor of 2. The densities were correlated by means of a modified Tait equation, while the viscosities were correlated both with the theory of Dymond and Assael and in terms of an empirical function of temperature and pressure. We also present correlations of the viscosity of dodecane and octadecane based on results that we published previously [Caudwell et al. Int. J. Thermophys. 2004, 25, 1340-1352]. Extensive comparisons with literature data are presented.
Compounds
# Formula Name
1 C8H18 octane
2 C10H22 decane
3 C8H10 1,3-dimethylbenzene
4 C10H12 1,2,3,4-tetrahydronaphthalene
5 C11H10 1-methylnaphthalene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating wire viscometry
  • 88
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • vibrating wire
  • 88
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating wire viscometry
  • 32
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • steady state vibrating wire instrument
  • 32
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating wire viscometry
  • 81
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • vibrating wire
  • 81
  • POMD
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • steady state vibrating wire instrument
  • 63
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • steady state vibrating wire instrument
  • 63
  • POMD
  • 5
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • steady state vibrating wire instrument
  • 74
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • steady state vibrating wire instrument
  • 74