Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density and Excess Properties of Aqueous N-Methyldiethanolamine Solutions from (298.15 to 338.15) K

Muhammad, A.[Ayyaz], Mutalib, M. I. A.[Mohamed I. Abdul], Murugesan, T.[Thanabalan], Shafeeq, A.[Amir]
J. Chem. Eng. Data 2008, 53, 9, 2217-2221
ABSTRACT
Densities (F) of pure and aqueous N-methyldiethanolamine (MDEA) solutions (wMDEA ) 0.3228 or 4 mol * kg-1 and wMDEA ) 0.4880 or 8 mol * kg-1) at (298.15 to 338.15) K were measured at atmospheric pressure and also correlated. The coefficients of thermal expansion (Rp) values were calculated from the experimental density data for the investigated compositions, using an empirical correlation. The excess molar volumes of aqueous MDEA solutions for mole fractions (0.0128 to 0.7531) were calculated from experimental densities at temperatures (298.15 to 338.15) K and correlated with the Redlich-Kister equation. The partial molar volumes of MDEA in water at infinite dilution and the change in volume were also determined using Redlich-Kister coefficients.
Compounds
# Formula Name
1 C5H13NO2 N-methyldiethanolamine
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:24
  • 9
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:24
  • 18
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:24
  • 135