Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Sound velocities of solutions of manganese(II), cobalt(II), nickel(II), copper(II), and zinc(II) perchlorates and chlorides in N,N-dimethylacetamide (DMA) and dimethylsulfoxide (DMSO) were measured at 298.15 K. Adiabatic compressibility coefficients of the solutions were determined, and apparent adiabatic molar compressibilities of the salts at infinite dilution were evaluated and discussed.

Compounds

#	Formula	Name
1	Cl2MnO8	manganese (II) perchlorate
2	Cl2CoO8	cobalt(II) perchlorate
3	Cl2NiO8	nickel perchlorate
4	Cl2CuO8	copper perchlorate
5	Cl2O8Zn	zinc perchlorate
6	Cl2Mn	manganese chloride
7	Cl2Co	cobalt chloride
8	Cl2Ni	nickel chloride (NiCl2)
9	Cl2Cu	copper chloride
10	Cl2Zn	zinc chloride
11	C4H9NO	N,N-dimethylethanamide
12	C2H6OS	dimethyl sulfoxide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	11	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	Sing-around technique in a fixed-path interferometer	1
POMD	11	Mass density, kg/m3 ; Liquid		Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	12	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	Sing-around technique in a fixed-path interferometer	1
POMD	12	Mass density, kg/m3 ; Liquid		Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	5
POMD	11 1	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 1	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 2	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	10
POMD	11 2	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	10
POMD	11 3	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 3	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 4	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 4; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 4	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 4; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 5	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 5; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 5	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 5; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 6	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 6	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 7	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 7	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 8	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 8; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 8	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 8; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 9	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 9; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 9	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 9; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	11 10	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 10; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	9
POMD	11 10	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 10; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	9
POMD	12 1	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	12
POMD	12 1	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	12
POMD	12 2	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	12
POMD	12 2	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	12
POMD	12 3	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	12 3	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	11
POMD	12 4	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 4; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	11
POMD	12 4	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 4; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	11
POMD	12 5	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 5; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	10
POMD	12 5	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 5; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	10
POMD	12 6	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	10
POMD	12 6	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	10
POMD	12 7	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	10
POMD	12 7	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	10
POMD	12 8	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 8; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	10
POMD	12 8	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 8; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	10
POMD	12 9	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 9; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	8
POMD	12 9	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 9; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	8
POMD	12 10	Speed of sound, m/s ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 10; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	8
POMD	12 10	Mass density, kg/m3 ; Liquid	Ratio of amount of solute to mass of solution, mol/kg - 10; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Vibrating tube method	8

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Adiabatic Compressibilities of Divalent Transition-Metal Perchlorates and Chlorides in N,N-Dimethylacetamide and Dimethylsulfoxide

Warminska, D.[Dorota], Placzek, A.[Anna], Koziel, H.[Hanna], Grzybkowski, W.[Waclaw]

ABSTRACT