Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibria for Propane (R290) + n-Butane (R600) at Various Temperatures

Seong, G.[Gimyeong], Yoo, K.-P.[Ki-Pung], Lim, J. S.[Jong Sung]
J. Chem. Eng. Data 2008, 53, 12, 2783-2786
ABSTRACT
Isothermal vapor-liquid equilibrium data for the binary mixture of propane (R290) + normal butane (R600) were measured at (273.15, 283.15, 293.15, 303.15, 313.15, and 323.15) K, respectively. The experiments were carried out using a continuous circulation-type equilibrium apparatus to measure temperature, pressure, and the compositions of the liquid and vapor phases. The experimental data were correlated with the Peng-Robinson equation of state (PR-EOS) using the Wong-Sandler mixing rule. The calculated results showed good agreement with experimental data. This system showed slightly negative deviation from Raoult s law and no azeotropes for all the temperature ranges studied here.
Compounds
# Formula Name
1 C3H8 propane
2 C4H10 butane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 6
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 6
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 82
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • CHROM:UFactor:2
  • 82