Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Thermodynamic Study of Phenyl Salicylate Solutions in Aprotic Solvents at Different Temperatures

Iqbal, M. J.[Muhammad Javed], Chaudhry, M. A.[Mansoora Ahmed]
J. Chem. Eng. Data 2009, 54, 2, 338-341
ABSTRACT
Phenyl salicylate is employed as a nervous system depressant as well as an intestinal antiseptic owing to its antibacterial activity upon hydrolysis in the small intestine. Various partial molar quantities, namely, apparent molar volume (V O), partial molar volume (V m), thermal expansion coefficient (R2), and ( Y2V m/ YT2), of phenyl salicylate in aprotic solvents, i.e., acetonitrile, dimethyl sulfoxide, tetrahydrofuran, and 1,4-dioxane, at T ) (293.15 to 313.15) K have been determined. The density and viscosity data were obtained with the help of a vibrating-tube densimeter and viscometer in a concentrarion range of (9.6 E 10-3 to 33.0 E 10-3) mol E kg-1. The viscosity data have been analyzed using the Jones-Dole equation and the derived parameter B has also been interpreted in terms of solute-solvent interactions.
Compounds
# Formula Name
1 C13H10O3 phenyl salicylate
2 C2H3N acetonitrile
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 6
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 6
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 48
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 48