ABSTRACT

The density, viscosity, refractive index, surface tension and ultrasonic velocity have been determined for 4-hydroxy 4-methyl pentanone with nitrobenzene or ethyl benzene over the entire composition range at temperatures of (303.15, 313.15, and 323.15) K. The viscosity values were fit to the models of Grundberg and Nissan, Hind, and McAllister. The thermophysical properties under study were fit to the Jouyban-Acree model. In addition, artificial neural networks were used to simulate all the thermophysical properties of liquid mixtures with mole fraction at (303.15, 313.15, and 323.15) K. The excess values were correlated using the Redlich-Kister polynomial equation to obtain their coefficients and standard deviations.

Compounds

#	Formula	Name
1	C6H12O2	4-hydroxy-4-methylpentan-2-one
2	C6H5NO2	nitrobenzene
3	C8H10	ethylbenzene
4	C7H8	toluene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid		Liquid Air at 1 atmosphere	RINGTE::UFactor:2	4
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:16	3
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:8	4
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:4	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:32	4
POMD	2	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid		Liquid Air at 1 atmosphere	RINGTE::UFactor:2	3
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:16	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:8	3
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:4	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:32	3
POMD	3	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid		Liquid Air at 1 atmosphere	RINGTE::UFactor:2	3
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:8	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:12	3
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:4	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:16	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	2 1	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid		Liquid Air at 1 atmosphere	RINGTE:UFactor:2	33
POMD	2 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:8	33
POMD	2 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:16	33
POMD	2 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI:UFactor:4	33
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:32	33
POMD	3 1	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid		Liquid Air at 1 atmosphere	RINGTE:UFactor:2	33
POMD	3 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:12	33
POMD	3 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	33
POMD	3 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI:UFactor:4	33
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:16	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Thermo Physical Properties of 4-Hydroxy 4-Methyl Pentanone with Nitrobenzene or Ethyl Benzene at Temperatures of (303.15, 313.15, and 323.15) K and a Pressure of 0.1 MPa

Baskaran, R., Kubendran, T. R.

ABSTRACT