Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and correlation of the thermal conductivity of methylcyclohexane and propylcyclohexane from 300 K to 600 K at pressures to 60 MPa

Perkins, R. A.[Richard A.], Hammerschmidt, U.[Ulf], Huber, M. L.[Marcia L.]
J. Chem. Eng. Data 2008, 53, 9, 2120-2127
ABSTRACT
New experimental data on the thermal conductivity of methylcyclohexane and propylcyclohexane are reported that allow the developement of wide-range correlations. These new experimental data, covering a temperature range of 300 K to 600 K and a pressure range of 0.1 MPa to 60 MPa, are used to develop correlations for the thermal conductivity. The experimental data reported here have an uncertainty of less than 1 % for measurements removed from the critucal pount and for gas at low pressures (less than 1 MPa). Based on the uncertainty of and comparisons with the present data, the thermal conductivity correlations for methylcyclohexane and propylcyclohexane are estimated to have a relative uncertainty of about 4 % at a 95 % confidence level. The present data include a contribution due to thermal radiation that increases in proportion to temperature cubed up to estimated value from 2 % to 3 % near 600 K.
Compounds
# Formula Name
1 C7H14 methylcyclohexane
2 C9H18 1-cyclohexylpropane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Hot wire method
  • 199
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Gas
  • Pressure, kPa; Gas
  • Temperature, K; Gas
  • Gas
  • Hot wire method
  • 133
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Gas
  • Pressure, kPa; Gas
  • Temperature, K; Gas
  • Gas
  • Hot wire method
  • 172
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Hot wire method
  • 686
  • POMD
  • 2
  • Thermal conductivity, W/m/K ; Gas
  • Pressure, kPa; Gas
  • Temperature, K; Gas
  • Gas
  • Hot wire method
  • 133
  • POMD
  • 2
  • Thermal conductivity, W/m/K ; Gas
  • Pressure, kPa; Gas
  • Temperature, K; Gas
  • Gas
  • Hot wire method
  • 129
  • POMD
  • 2
  • Thermal conductivity, W/m/K ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Hot wire method
  • 406