Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Thermodynamic Properties of Inorganic Salts in Nonaqueous Solvents. V. Apparent Molar Volumes and Compressibilities of Divalent Transition Metal Bromides in N,N-Dimethylformamide

Warminska, D.[Dorota], Placzek, A.[Anna], Grzybkowski, W.[Waclaw]
J. Chem. Eng. Data 2009, 54, 2, 220-226
ABSTRACT
Densities at (283.15, 293.15, 298.15, 303.15, 313.15, 323.15, and 333.15) K and sound velocities at 298.15 K of divalent transition metal bromides in N,N-dimethylformamide have been measured. From these data, apparent molar volumes and apparent molar isentropic compressibilities have been evaluated. The results have been discussed in terms of complex formation.
Compounds
# Formula Name
1 C3H7NO dimethylformamide
2 Br2Mn manganese(II) bromide
3 Br2Co cobalt(II) bromide
4 Br2Ni nickel bromide
5 Br2Cu copper dibromide
6 Br2Zn zinc bromide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pulse-echo method
  • 1
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 2
  • Vibrating tube method
  • 91
  • POMD
  • 1
  • 3
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 3
  • Pulse-echo method
  • 8
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Liquid
  • Crystal - 3
  • Vibrating tube method
  • 91
  • POMD
  • 1
  • 4
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 4
  • Pulse-echo method
  • 8
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Liquid
  • Crystal - 4
  • Vibrating tube method
  • 77
  • POMD
  • 1
  • 5
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 5; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 5
  • Pulse-echo method
  • 9
  • POMD
  • 1
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 5; Liquid
  • Liquid
  • Crystal - 5
  • Vibrating tube method
  • 84
  • POMD
  • 1
  • 6
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 6; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 6
  • Pulse-echo method
  • 12
  • POMD
  • 1
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 6; Liquid
  • Liquid
  • Crystal - 6
  • Vibrating tube method
  • 91