Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric, Transport and Surface Properties of [bmim][MeSO4] and [emim][EtSO4] Ionic Liquids As a Function of Temperature

Fernandez, A.[Adela], Garcia, J.[Julian], Torrecilla, J. S.[Jose S.], Oliet, M.[Mercedes], Rodriguez, F.[Francisco]
J. Chem. Eng. Data 2008, 53, 7, 1518-1522
ABSTRACT
The effect of temperature on density, viscosity, and surface tension of 1-butyl-3-methylimidazolium methylsulfate [bmim][MeSO4] and 1-ethyl-3-methylimidazolium ethylsulfate [emim][EtSO4] ionic liquids (ILs) has been determined. Viscosity values of both ILs above-mentioned have been modeled by the Arrhenius equation and the Vogel-Fulcher-Tammann expression. Density, viscosity, surface tension, and surface excess energy of [bmim][MeSO4] and [emim][EtSO4] decreases as the temperature increases.
Compounds
# Formula Name
1 C9H18N2O4S 1-butyl-3-methylimidazolium methyl sulfate
2 C8H16N2O4S 1-ethyl-3-methylimidazolium ethyl sulfate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Drop weight
  • 4
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Falling or rolling sphere viscometry
  • 6
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Vibrating tube method
  • 13
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Drop weight
  • 4
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Falling or rolling sphere viscometry
  • 7
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Vibrating tube method
  • 13