ABSTRACT

Density in the temperature interval (293.15 to 323.15) K and excess enthalpy at 303.15 K are determined for 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4] + ethanol or + nitromethane and 1-butyl- 3-methylimidazolium methylsulfate [BMIM][MeSO4] + ethanol or + nitromethane. Excess molar volumes are calculated at several temperatures from density data. Both excess properties are fitted to a Redlich-Kisterbased equation, and results are discussed in terms of the chemical nature of the compounds that form the mixtures.

Compounds

#	Formula	Name
1	C8H15BF4N2	1-butyl-3-methylimidazolium tetrafluoroborate
2	C9H18N2O4S	1-butyl-3-methylimidazolium methyl sulfate
3	C2H6O	ethanol
4	CH3NO2	nitromethane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	12
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:8	56
POMD	4 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	10
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	60
POMD	3 2	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	11
POMD	3 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:8	64
POMD	4 2	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	9
POMD	4 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	56

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Excess Enthalpies for Ionic Liquids + Ethanol or + Nitromethane

Iglesias-Otero, M. A.[Manuel A.], Troncoso, J.[Jacobo], Carballo, E.[Enrique], Romani, L.[Luis]

ABSTRACT