ABSTRACT

Liquid-liquid equilibrium data are critical for designing the extraction equipment or calculating the thermodynamic limit of a given separation. In this work, the LLE data were measured for the cyclohexane + (benzene, + toluene, + ethylbenzene, or + o-xylene) + 4-methyl-N-butyl pyridinium tetrafluoroborate ([bmpy]BF4) systems at 303.15 K under atmospheric pressure. The consistency of the measured LLE data was tested using the Othmer-Tobias correlation and the root-mean-square deviation (rmsd) in the mass fraction of [bmpy]BF4 in the lower phase and the average value of the absolute difference (AAD) between experimental mass fraction of cyclohexane in the upper phase and that calculated using the Othmer-Tobias correlation.

Compounds

#	Formula	Name
1	C10H16BF4N	1-butyl-4-methylpyridinium tetrafluoroborate
2	C6H6	benzene
3	C7H8	toluene
4	C8H10	ethylbenzene
5	C8H10	1,2-dimethylbenzene
6	C6H12	cyclohexane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 6 1	Mole fraction - 2 ; Liquid mixture 1 Mole fraction - 6 ; Liquid mixture 2 Mole fraction - 2 ; Liquid mixture 2	Mole fraction - 6; Liquid mixture 1	Temperature, K; Liquid mixture 1 Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	14
POMD	2 6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 6; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	28
POMD	3 6 1	Mole fraction - 3 ; Liquid mixture 1 Mole fraction - 6 ; Liquid mixture 2 Mole fraction - 3 ; Liquid mixture 2	Mole fraction - 6; Liquid mixture 1	Temperature, K; Liquid mixture 1 Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	14
POMD	3 6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 6; Liquid Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	28
POMD	4 6 1	Mole fraction - 4 ; Liquid mixture 1 Mole fraction - 6 ; Liquid mixture 2 Mole fraction - 4 ; Liquid mixture 2	Mole fraction - 6; Liquid mixture 1	Pressure, kPa; Liquid mixture 1 Temperature, K; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	14
POMD	4 6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 6; Liquid Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	28
POMD	5 6 1	Mole fraction - 5 ; Liquid mixture 1 Mole fraction - 6 ; Liquid mixture 2 Mole fraction - 5 ; Liquid mixture 2	Mole fraction - 6; Liquid mixture 1	Pressure, kPa; Liquid mixture 1 Temperature, K; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	17
POMD	5 6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 6; Liquid Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Pycnometric method	34

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid-Liquid Equilibrium of Ternary Systems of Cyclohexane + (Benzene, + Toluene, + Ethylbenzene, or + o-Xylene) + 4-Methyl-N-butyl Pyridinium Tetrafluoroborate Ionic Liquid at 303.15 K

Abu-Eishah, S. I.[Samir I.], Dowaidar, A. M.[Ali M.]

ABSTRACT