Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physiochemical Properties of Several Aqueous Potassium Amino Acid Salts

van Holst, J.[Jacco], Kersten, S. R. A.[Sascha R. A.], Hogendoorn, K. J. A.[Kees J. A.]
J. Chem. Eng. Data 2008, 53, 6, 1286-1291
ABSTRACT
Aqueous amino acid salt solutions might be an attractive alternative over traditional alkanolamines in the removal of CO2 from flue gases especially because of their oxidative stability and negligible volatility. The density and viscosity of the aqueous solutions of the potassium salts of the following amino acids have been measured: -alanine, 6-aminohexanoic acid, L-arginine, L-aspartic acid, L-glutamic Acid, DL-methionine, L-phenylalanine, L-proline, and sarcosine. Data are reported in the temperature range of (25 to 60) deg C and concentration range of (0.25 to 3.5) mol *L-1. The data could be correlated accurately with relatively simple relations. The physical solubility of N2O in the same amino acid salt solutions was also measured at a temperature of 298 K and a concentration of 0.5 mol *L-1 of the amino acid salt. Using the N2O/CO2 analogy on one hand and Schumpe s method on the other, the physical solubility of CO2 in these solutions was estimated. Both methods yielded results very close to each other.
Compounds
# Formula Name
1 H2O water
2 C3H6KNO2 potassium Salt of sarcosine
3 C3H6KNO2 potassium Salt of B-alanine
4 C6H12KNO2 potassium Salt of 6-aminohexanoic acid
5 C4H6KNO4 potassium (S)-2-amino-3-carboxypropanoate
6 C5H8KNO2 potassium L-prolinate
7 C5H8KNO4 potassium (S)-2-amino-4-carboxybutanoate
8 C5H10KNO2S potassium salt of DL-methionine
9 C6H13KN4O2 potassium L-argininate
10 C9H10KNO2 potassium L-phenylalaninate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 30
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 30
  • POMD
  • 1
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 35
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 35
  • POMD
  • 1
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 30
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 30
  • POMD
  • 5
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 30
  • POMD
  • 5
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 30
  • POMD
  • 1
  • 6
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 35
  • POMD
  • 1
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 35
  • POMD
  • 1
  • 7
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 30
  • POMD
  • 1
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 30
  • POMD
  • 1
  • 8
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 8; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 30
  • POMD
  • 1
  • 8
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 8; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 30
  • POMD
  • 1
  • 9
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 9; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 20
  • POMD
  • 1
  • 9
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 9; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 20
  • POMD
  • 1
  • 10
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 10; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 30
  • POMD
  • 1
  • 10
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 10; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:32
  • 30