Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of CO2 in a Choline Chloride + Urea Eutectic Mixture

Li, X.[Xuemin], Hou, M.[Minqiang], Han, B.[Buxing], Wang, X.[Xiaoling], Zou, L.[Lizhuang]
J. Chem. Eng. Data 2008, 53, 2, 548-550
ABSTRACT
The solubility of CO2 in choline chloride + urea eutectic mixtures was determined at 313.15 K, 323.15 K, and 333.15 K under pressures up to 13 MPa. The mole ratios of choline chloride to urea selected were 1:1.5, 1:2, and 1:2.5. The Henry s constants and enthalpy of solution of the gas were calculated from the solubility data. The solubility of CO2 in the mixtures increased with increasing pressure, and the solubility is more sensitive to pressure in the low-pressure range. The solubility of CO2 in the mixtures decreased with increasing temperature at all the pressures. The enthalpy of solution is negative at all conditions.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 C5H14ClNO choline chloride
3 CH4N2O urea
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Amount ratio of component to other component of binary solvent - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • gravimetric method
  • 68