Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measuring Surface Tension of Liquids at High Temperature and Elevated Pressure

Chen, Z.[Zhiqiang], Xia, S.[Shuqian], Ma, P.[Peisheng]
J. Chem. Eng. Data 2008, 53, 3, 742-744
ABSTRACT
In this paper, an apparatus used to measure the surface tension at high temperature and elevated pressure was developed, based on the differential maximum bubble pressure method. As standard solvents, the surface tensions of methanol, ethanol, and benzyl benzoate were measured over a range of temperatures and pressures. The results were compared with the literature values, and the relative uncertainty of measurement is less than 2 %. The surface tensions of benzene, toluene, p-, o-, m-xylene, and the binary mixture of p-xylene + benzene were measured at 1.6 MPa, from (80 to 200) deg C.
Compounds
# Formula Name
1 CH4O methanol
2 C14H12O2 benzyl benzoate
3 C6H6 benzene
4 C7H8 toluene
5 C8H10 1,4-dimethylbenzene
6 C8H10 1,2-dimethylbenzene
7 C8H10 1,3-dimethylbenzene
8 N2 nitrogen
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Maximal bubble pressure
  • 5
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Maximal bubble pressure
  • 7
  • POMD
  • 1
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 4
  • POMD
  • 3
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 7
  • POMD
  • 4
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 7
  • POMD
  • 5
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 7
  • POMD
  • 6
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 7
  • POMD
  • 7
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 7
  • POMD
  • 3
  • 5
  • 8
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mole fraction - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Maximal bubble pressure
  • 42