Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Thermal Conductivity of Aqueous Na2CO3 at High Temperatures and High Pressures

Akhmedova-Azizova, L. A. A.[Lala A.], Babaeva, S. S.[Sevinch Sh.]
J. Chem. Eng. Data 2008, 53, 2, 462-465
ABSTRACT
The thermal conductivity of three aqueous Na2CO3 solutions of molality (0.4966, 1.0483, and 1.6650) mol * kg-1 has been measured with a concentric-cylinder (steady-state) technique. Measurements were made at three isobars, (0.1, 10, and 30) MPa. The range of temperatures was (293.15 to 627.06) K. The total uncertainty of thermal conductivity, pressure, temperature, and molality measurements was estimated to be less than 2 %, 0.05 %, 30 mK, and 0.02 %, respectively. The experimental and calculated values of thermal conductivity for pure water from IAPWS formulation show excellent agreement within their experimental uncertainties (AAD within 0.44 %) in the temperature range from (308.4 to 704.2) K and at pressures up to 60 MPa. Correlation equations for thermal conductivity of the solutions studied were obtained as a function of temperature, pressure, and composition by a least-squares method from the experimental data. The AAD between measured and calculated values from this correlation equation for the thermal conductivity was (0.5 to 0.7) %.
Compounds
# Formula Name
1 H2O water
2 CNa2O3 sodium carbonate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Thermal conductivity, W/m/K ; Liquid
  • Pressure, kPa; Liquid
  • Molality, mol/kg - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Coaxial cylinder method
  • 75