Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Sebacic Acid in Binary Water + Ethanol Solvent Mixtures

Xia, Q.[Qing], Zhang, F.-B.[Feng-Bao], Zhang, G.-L.[Guo-Liang], Ma, J.-C.[Jian-Cheng], Zhao, L.[Lei]
J. Chem. Eng. Data 2008, 53, 3, 838-840
ABSTRACT
Solubilities of sebacic acid in binary ethanol + water solvent mixtures were measured by the dynamic method using a laser monitoring observation technique at a temperature range from (288 to 352) K. The mole fraction of ethanol in the solvent mixtures ranges from 0 to 1. The melting temperature and enthalpy of fusion of sebacic acid were determined by differential scanning calorimetry. The experimental results show that the slope of the solubility-temperature curve increases significantly with an increase in the mole fraction of ethanol in the solvent. The Wilson equation is applied to describe measured systems. The model parameters of the Wilson equation were expressed as a function of temperature.
Compounds
# Formula Name
1 C10H18O4 1,10-decanedioic acid
2 C2H6O ethanol
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 11
  • POMD
  • 2
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 17
  • POMD
  • 2
  • 1
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 81