Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solid-Liquid Equilibria for the CO2 + R152a and N2O + R152a Systems

Di Nicola, G.[Giovanni], Giuliani, G.[Giuliano], Polonara, F.[Fabio], Santori, G.[Giulio], Stryjek, R.[Roman]
J. Chem. Eng. Data 2007, 52, 6, 2451-2454
ABSTRACT
A recently built experimental setup was employed for the estimation of the solid-liquid equilibria of alternative refrigerant systems. The behavior of two binaries, i.e., carbon dioxide + 1,1-difluoroethane (CO2 + R152a) and nitrous oxide + 1,1-difluoroethane (N2O + R152a), was measured down to temperatures of 132 K. The triple points of CO2 and N2O were measured to confirm the reliability of the apparatus. The triple point of R152a was also measured; however, the pressure at the triple point for this fluid was too low to accurately measure with the current apparatus. All triple-point data measured revealed a generally good consistency with the literature. The results obtained for the mixtures were interpreted by means of the Schroder equation.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 N2O nitrous oxide
3 C2H4F2 1,1-difluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal
  • Crystal
  • Liquid
  • Gas
  • closed cell
  • 1
  • POMD
  • 1
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Gas
  • DTA
  • 1
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Crystal
  • Crystal
  • Liquid
  • Gas
  • closed cell
  • 1
  • POMD
  • 2
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Gas
  • DTA
  • 1
  • POMD
  • 3
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Gas
  • DTA
  • 1
  • POMD
  • 3
  • 1
  • Triple point temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Crystal - 3
  • Gas
  • enthalpy/time analysis
  • 4
  • POMD
  • 3
  • 1
  • Triple point temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Crystal - 1
  • Gas
  • enthalpy/time analysis
  • 12
  • POMD
  • 3
  • 2
  • Triple point temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 3
  • Gas
  • enthalpy/time analysis
  • 5
  • POMD
  • 3
  • 2
  • Triple point temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 2
  • Gas
  • enthalpy/time analysis
  • 9