Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosities of Fatty Mixtures: Experimental Data and Prediction

Goncalves, C. B.[Cintia B.], Ceriani, R.[Roberta], Rabelo, J.[Juliana], Maffia, M. C.[Maria Cristina], Meirelles, A. J. A.[Antonio J. A.]
J. Chem. Eng. Data 2007, 52, 5, 2000-2006
ABSTRACT
Viscosity data of fatty compounds and their mixtures are important for designing equipment for the oil industry, including edible, as some vegetable oils, and nonedible purposes, as biodiesel. To expand the data bank gathered from the literature, the present work reports viscosity data of fatty mixtures found in the oil and fat industry, such as mixtures of fatty acids, methyl esters, and triacylglycerols, over a large range of temperatures. Viscosities of these fatty mixtures as well as viscosity data taken from the literature were predicted by known methods, such as the modified Kay s rule, the Kendall and Moore model, and GC-UNIMOD. In general, the three models presented a good representation of the kinematic viscosity of fatty mixtures. For the majority of cases (or 77.1 %), the average relative deviations (ARD) obtained were not higher than 10 %.
Compounds
# Formula Name
1 C18H34O2 (Z)-9-octadecenoic acid
2 C27H50O6 1,2,3-propanetriol trioctanoate
3 C10H20O2 decanoic acid
4 C57H104O6 1,2,3-tri(cis-9-octadecenoyl)glycerol
5 C15H30O2 methyl tetradecanoate
6 C17H34O2 methyl hexadecanoate
7 C19H36O2 methyl cis-9-octadecenoate
8 C18H32O2 (Z,Z)-9,12-octadecadienoic acid
9 C57H98O6 trilinolein
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 4
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 8
  • POMD
  • 1
  • 9
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 8
  • POMD
  • 1
  • 3
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 14
  • POMD
  • 8
  • 4
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 7
  • POMD
  • 8
  • 9
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 7
  • POMD
  • 3
  • 2
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 21
  • POMD
  • 6
  • 7
  • 5
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Mole fraction - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 6