Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibria for Propane (R-290) + 1,1,1,2,3,3,3-Heptafluoropropane (HFC-227ea) at Various Temperatures

Lim, J. S.[Jong Sung], Seong, G.[Gimyeong], Roh, H.-K.[Hee-Kook]
J. Chem. Eng. Data 2007, 52, 6, 2250-2256
ABSTRACT
Isothermal vapor-liquid equilibrium data for propane + 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) were measured at (273.15, 283.15, 293.15, 303.15, 313.15, and 323.15) K, respectively. The experiments were carried out using a circulation-type equilibrium apparatus to measure temperature, pressure, and the compositions of the liquid and vapor phases. The experimental data were well correlated with the Peng-Robinson equation of state (PR-EOS) using the Wong-Sandler mixing rules and the Carnahan-Starling-De Santis equation of state (CSDEOS). This system shows strong positive azeotrope.
Compounds
# Formula Name
1 C3H8 propane
2 C3HF7 1,1,1,2,3,3,3-heptafluoropropane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 6
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 6
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:4
  • 79
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 79