ABSTRACT

Densities of mixtures of 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) with acetonitrile over the entire composition range at T = (293.15 to 343.15) K and with benzene and 1-propanol over the miscible composition range at T = (293.15 to 343.15) K were measured by a vibrating tube densimeter. Density measurements were used to compute the excess molar volumes, VE. The VE values have been fitted to the Redlich-Kister equation. VE values are negative for all the mixtures over the miscible range and become more negative with increasing temperature. The VE values for benzene mixtures are the most negative in the investigation.

Compounds

#	Formula	Name
1	C8H15F6N2P	1-butyl-3-methylimidazolium hexafluorophosphate
2	C8H15BF4N2	1-butyl-3-methylimidazolium tetrafluoroborate
3	C6H6	benzene
4	C2H3N	acetonitrile
5	C3H8O	propan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	8
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	8
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	8
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	8
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	8
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	72
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	88
POMD	3 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	72
POMD	5 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	72
POMD	4 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:6	88

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities of Ionic Liquids, 1-Butyl-3-methylimidazolium Hexafluorophosphate and 1-Butyl-3-methylimidazolium Tetrafluoroborate, with Benzene, Acetonitrile, and 1-Propanol at T = (293.15 to 343.15) K

Huo, Y.[Yan], Xia, S.[Shuqian], Ma, P.[Peisheng]

ABSTRACT